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Microporous mixed-metal (Na/Cu) mixed-ligand (flexible/rigid) metal–organic framework for photocatalytic H2 generation For the first time, we report a cost-effective mixed-metal (Na/Cu) mixed-ligand (flexible/rigid) metal–organic framework H1.5[Na0.5Cu2(L1)(L2)(H2O)]·5.5H2O (Na/Cu–MOF; H2L1 = 4,4'-(4-(4H-1,2,4-triazol-4-yl)phenylazanediyl)dibenzoic acid; H4L2 = citric acid).
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