Is this you? As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.
Claim your profile
Articles by Antonio Mezzetti
Retraction: The Manganese(I)‐Catalyzed Asymmetric Transfer Hydrogenation of Ketones: Disclosing the Macrocylic Privilege
Retraction The above article from Angewandte Chemie International Edition, published online on 14 November 2019 in Wiley Online Library (wileyonlinelibrary.com, DOI: 10.1002/anie.201912605), and in print in Volume 59, pp. 187–191, has been retracted by agreement between the authors, Alessandro Passera and Prof. Dr. Antonio Mezzetti (corresponding author), the journal's interim Editor‐in‐Chief Committee, and Wiley‐VCH Verlag GmbH&Co. KGaA, Weinheim.
The Manganese(I)‐Catalyzed Asymmetric Transfer Hydrogenation of Ketones: Disclosing the Macrocylic Privilege
Email or Customer ID "Please check your email for instructions on resetting your password. If you do not receive an email within 10 minutes, your email address may not be registered, and you may need to create a new Wiley Online Library account.
The Manganese(I)‐Catalyzed Asymmetric Transfer Hydrogenation of Ketones: Disclosing the Macrocyclic Privilege
Communication Antonio Mezzetti Corresponding Author E-mail address: mezzetti@inorg.chem.ethz.ch ETH Zürich, Chemistry and Applied Biosciences, Vladimir-Prelog-Weg 2, HCI H 235, 8093 Zürich, SWITZERLAND Search for more papers by this author PDF PDF Share Abstract The bis(carbonyl) manganese(I) complex [Mn(CO)2(1)]Br (2) with a chiral (NH)2P2 macrocyclic ligand (1) catalyzes the asymmetric transfer hydrogenation (ATH) of polar double bonds with 2‐propanol as hydrogen source.
Which future for stereogenic phosphorus? Lessons from P* pincer complexes of iron(II)
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
Asymmetric Transfer Hydrogenation with a Bifunctional Iron(II) Hydride: Experiment Meets Computation
Abstract Hydride cis-β-[FeH(CNCEt3)(1)]BF4 (5) (1 is a chiral N2P2 macrocycle) is the catalytically active species in the asymmetric transfer hydrogenation of ketones formed upon reaction of [Fe(CNCEt3)2(1)](BF4)2 (3) with base. Stoichiometric reactions show that hydride 5 is formed by H-elimination from the 2-propoxo complex [Fe(OiPr)(CNCEt3)(1)]BF4 (8a) and inserts the C═O bond of acetophenone to give the diastereoisomeric alcoholato complexes [Fe(OCH(Me)Ph)(CNCEt3)(1)]BF4 (10R and 10S).
Show More
loading
Actions
Is this you?
As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.Get in touch with Antonio
Contact Antonio, search articles and posts on X, monitor coverage, and track replies from one place.
Learn more about Muck Rack