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Articles by Anwei Wang
Ligand-modulated metal–radical polarity match enables general 1,2-dicarbofunctionalization of ethylene
Abstract Leveraging transition metal catalysis to direct multiple radical intermediates towards a single desired product offers many synthetic opportunities while presenting an important chemoselectivity challenge arising from selectivity in radical capture by the catalyst. How mechanistic design precisely tunes this selectivity remains limited, constraining the rational design of efficient catalytic systems.
Highly Active Co2+ Species Constructed in CuCoFe Metahydrotacite‐B Realize the Efficient Oxidative Cleavage of Vicinal Diols Without Any Additives
Conflicts of Interest The authors declare no conflicts of interest. Supporting Information Filename Description aoc70338-sup-0001-Supplementary_Material.docxWord 2007 document , 18.5 MB FIGURE S1: The photographs of the reactor and the reaction. SCHEME S1: Scale-up experiment. TABLE S1: The atomic molar ratio, mass, and surface area of Co-containing samples. aoc70338-sup-0001-Supplementary_Material.docx. TABLE S2: The NCo-surf and nCo-surf of the prepared samples.
Cooperation between Cu+ and Cu2+ species in CuCoAl layered double hydroxide and substrate promoting effect afford a really simple protocol for the efficient synthesis of quinazolines
Cooperation between Cu+ and Cu2+ species in CuCoAl layered double hydroxide and substrate promoting effect afford a really simple protocol for the efficient synthesis of quinazolines A really simple and efficient catalytic protocol for the construction of quinazolines from alcohol and diamine has been developed based on CuCoAl layered double hydroxide (CuCoAl-LDH) in the study.
A simple and convenient strategy for the oxidation of C(sp3)-H bonds based on γ-valerolactone
A simple and convenient strategy for the oxidation of C(sp3)–H bonds based on γ-valerolactone† The aerobic oxidation of C(sp3)–H bonds is an important issue in organic synthesis, and hydrogen atom transfer (HAT) is an effective process to initiate the oxidation reaction. Here, we demonstrate an innovative strategy for the oxidation of C(sp3)–H bonds based on γ-valerolactone, which can be produced from biomass.
A simple and convenient strategy for the oxidation of C(sp3)‒H bonds based on γ-valerolactone
A simple and convenient strategy for the oxidation of C(sp3)‒H bonds based on γ-valerolactone The aerobic oxidation of C(sp3)–H bonds is an important issue in organic synthesis, and hydrogen atom transfer (HAT) is an effective process to initiate the oxidation reaction. Here, we demonstrate an innovative strategy for the oxidation of C(sp3)‒H bonds based on γ-valerolactone, which can be produced from biomass.
Efficiently Aerobic Dehydrogenation of N‐Heterocycles and Hydrocarbons over MnAl Oxides
Graphical Abstract An inexpensive, simple and green catalytic system has been developed for the aerobic dehydrogenation of N-heterocycles and hydrocarbons based on MnAl oxides. Good application potential was demonstrated by gram scale synthesis and broad substrate scope. Mechanistic studies indicated that dehydrogenation proceeds mainly via an electron transfer mechanism.
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