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Abstract Cathode interlayers create interfacial dipoles in organic solar cells to maximize device efficiency. However, the dipoles are highly dependent on the molecular orientation of the interlayers, which remain challenging to be controlled. Here, based on the amphiphilic nature of the interlayers, we show a stepwise film deposition approach using a polar solvent for active layer pretreatment and a bipolar solvent for subsequent interlayer self assembly.
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