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Abstract Single fluorescent molecules embedded in the bulk of host crystals have proven to be sensitive probes of the dynamics in their nano environment, thanks to their narrow (about 30–50 MHz or 0.1–0.2 μeV) optical linewidth of the 0-0 zero-phonon line (0-0 ZPL) at cryogenic temperatures.
Abstract Electron states above the vacuum level are known to play an important role in secondary electron processes, such as photoelectron emission and secondary electron emission where they act as “final” (or better “intermediate”) states from which an electron is emitted to the vacuum. However, despite their relevance, these states are typically not well known, nor independently investigated, mostly due to a lack of proper spectroscopic techniques.
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