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Efficient and Green: Biowaste-Derived N-rich Carbon for Palladium-Catalyzed CO Gas-Free Carbonylative Annulation with DFT Insights This study presents a catalytic approach utilizing nitrogen-rich carbon (NRC-FS-4) derived from fish scales, a biowaste material, as a sustainable and robust support for palladium nanoparticles (PdNPs).
3. Experimental 3.1. Materials The Artocarpus heterophyllus (jackfruit) seed was obtained from Tumkur district, Karnataka, India. The seeds were thoroughly washed with tap and distilled water consecutively, and then fragmented. The dried fragments were ground by mechanical grinding and then by mortar and pestle. Pd(OAc)2 (99% pure), CH3COOH, CH3COONa, OPD (extra-pure AR, 99%), 30% H2O2, D-(+)-glucose (≥99.5%), L-glutathione, GOx (ex.
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