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Synthesis and study of Fe - Pd interactions in unsymmetric Pd(II) complexes with phosphinoferrocene guanidine ligands Readily available phosphinoferrocene guanidines coordinate Pd(II) as P,N-chelating or κ3P,N,Fe-bound ligands. As the latter, they give rise to the first donor-asymmetric complexes featuring Fe–Pd dative bonds, which were studied using direct (spectroscopic and electrochemical) methods and theoretical (DFT) approaches.
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