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Visible light-induced gem-difluoroallylation of [1.1.1]propellane to access gem-difluoroallylic bicyclo[1.1.1]pentanes† Hui Zhu,a Shengxing Wu,a Bingbin Zhu,a Jiacheng Li,a Deyou Lan,a Wenhao Xu,a Gongcheng Xu,a Yu Zhu,a Chuanming Yu a and Xinpeng Jiang *a Abstract Bicyclo[1.1.1]pentanes (BCPs) represent an important compound class often used as linear spacer units to enhance pharmacokinetic profiles in modern drug design.
Synthesis of 1-azido-3-heteroaryl bicyclo[1.1.1]pentanes via azidoheteroarylation of [1.1.1]propellane† Herein, we report a novel reaction for the synthesis of 1-azido-3-heteroaryl bicyclo[1.1.1]pentanes via azidoheteroarylation of [1.1.1]propellane.
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