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Articles by Bisma Rasool
DMSO-K2S2O8 mediated iodine-free conversion of glycal C-3 ether to 3-enopyranones: synthesis of furo[3,2-c] pyrans
DMSO–K2S2O8 mediated iodine-free conversion of glycal C-3 ether to 3-enopyranones: synthesis of furo[3,2-c] pyrans† A straightforward, highly efficient, and regioselective method for directly converting 3-O-benzylated and silylated glycals into their corresponding enones has been developed using a DMSO–K2S2O8 reagent system. This reaction is scalable to gram quantities under mild conditions, achieving up to 80% yields.
Synthesis of aryl enopyranones directly from glycals and aromatic halides to access 2-deoxy-β-C-aryl glycosides
Synthesis of aryl enopyranones directly from glycals and aromatic halides to access 2-deoxy-β-C-aryl glycosides† An efficient synthesis of aryl enopyranones via an oxidative Heck-type coupling reaction between ether protected D/L-glycals and different aryl halides is developed.
Peroxodisulfate-assisted synthesis of 2-thiocyanato glycals and their transformation to C-2-thio acrylo/aryl nitrile-substituted glycals
Peroxodisulfate-assisted synthesis of 2-thiocyanato glycals and their transformation to C-2-thio acrylo/aryl nitrile-substituted glycals† An efficient regioselective method to attach thiocyanato groups at the β-position of enol double bonds in sugar enol ethers using KSCN and potassium persulfate has been developed.
Thieme E-Journals - Synlett
Buy Article Permissions and Reprints All articles of this category Since their discovery in the 1950s, C-nucleosides have piqued the interest of both biologists and medicinal chemists. In this regard, C-nucleosides and their synthetic analogues have resulted in promising leads in drug design. Concurrently, advances in chemical syntheses have contributed to structural diversity and drug discovery efforts. Convergent and modular approaches to synthesis have gained much attention in this regard.
Switchable reactivity of 2-benzoyl glycals towards stereoselective access of 1-3 and 1-1 S/O linked disaccharides
Switchable reactivity of 2-benzoyl glycals towards stereoselective access of 1-3 and 1-1 S/O linked disaccharides Irshad Ahmad Zargar, Bisma Rasool, Norein Sakander and Debaraj Mukherjee Abstract We have developed a synthesis of 1-3 and 1-1 disaccharides from 2-benzoyl glycal and anomeric thiol and/or hydroxy sugar acceptors under mild conditions at room temperature.
Pd Catalyzed Synthesis of Hetero 1,2-Interlinked C-Disaccharides by Coupling of iodo Glycals with Glycals
Pd Catalyzed Synthesis of Hetero 1,2-Interlinked C-Disaccharides by Coupling of iodo Glycals with Glycals Bisma Rasool, Irshad Ahmad Zargar, Nazar Hussain and Debaraj Mukherjee Abstract A facile synthesis of C1-C2 interlinked disaccharides is achieved from readily available iodo-glycals and unsubstituted glycals .
Ni Catalyzed Domino Transformation of Enopyranoses and 2-Iodo Phenols/Anilines to Pyrano cis fused dihydro-Benzofurans/Indoles
Ni Catalyzed Domino Transformation of Enopyranoses and 2-Iodo Phenols/Anilines to Pyrano cis fused dihydro-Benzofurans/Indoles Monika Bhardwaj, Bisma Rasool and Debaraj Mukherjee Abstract Ni catalyzed direct access to various pyrano cis fused dihydro benzofurans and indoles from unsaturated enopyranoses and o-iodo phenols/anilines is developed.
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