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In a preliminary communication, it was reported that TpW(NO)(PMe)(η-benzene) () could be combined with analkylindoline and an ammonium triflate salt to form an η-indolinium complex ( Scheme ). (23) This system has the ability to react with electrophiles to give a stable, double cationic species (), which can then react with nucleophiles to form a tetrahydroindolium complex ().
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