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Single crystals of DyRh2Si2 and HoRh2Si2 were investigated by thermal expansion and magnetostriction. The different types of magnetic order can clearly be seen in these measurements, particularly the canting of the moments away from the crystallographic c direction below about 12 K and the spin flip for magnetic field applied along the c direction.
Within the usually used approximations the Kondo model predicts that both the low temperature valence, 3 − Δn (0), and the temperature scale, T , on which the valence changes occur will increase with increasing Kondo scale T (see e.g. ref. 30, n.b. Supplementary Note 5). Figure 4b clearly shows that there is indeed a very nice correlation between Δn (0) measured with RXES and the thermodynamically determined T .
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