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Dichloromethane replacement: towards greener chromatography via Kirkwood–Buff integrals† Julie Lynch, *a James Sherwood, a C. Rob McElroy, a Jane Murrayb and Seishi Shimizu *c Abstract Dichloromethane (DCM) is a useful and advantageous solvent used in pharmaceutical development due to its low cost, miscibility with other organic solvents, high volatility, and ability to solubilize drug molecules of variable polarities and functionalities.
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