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Articles by Chenghai Lu
Quantifying Effective Dehydrated Ion Sizes Based on Pore‐Ion Steric Properties to Predict Separation Selectivity
Conflict of Interests The authors declare no conflict of interest. Data Availability Statement The data that support the findings of this study are available from the corresponding author upon reasonable request. Supporting Information Filename Description anie70263-sup-0001-SuppMat.docx4.5 MB Supporting Information References 1, , Science 2011, 333, 712–717, https://doi.org/10.1126/science.1200488. 2, , , , , , , , Chem. Soc. Rev. 2022, 51, 672–719, https://doi.org/10.1039/D0CS01599G. 3, AIChE J.
Combined Effect of Electrostatic Interaction and Steric Sieving during Ion Transport in Nanochannels
Steric Hindrance-Induced Dehydration Promotes Cation Selectivity in Trans-Subnanochannel Transport
Dehydration is a basic phenomenon in ion transport through confined nanochannels, but how it affects ion trans-membrane selectivity has not been understood due to a lack of characterization techniques and suitable pore structures.
In Situ Characterization of Dehydration during Ion Transport in Polymeric Nanochannels
The transport of hydrated ions across nanochannels is central to biological systems and membrane-based applications, yet little is known about their hydrated structure during transport due to the absence of in situ characterization techniques. Herein, we report experimentally resolved ion dehydration during transmembrane transport using modified in situ liquid ToF-SIMS in combination with MD simulations for a mechanistic reasoning.
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