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Direct hydrogenation of CO2 into formate using Iridium catalyst containing proton responsive imidazoline-amide ligands A series of air-stable, water-soluble iridium catalysts featuring imidazoline-amide ligands have been developed for the aqueous-phase hydrogenation of CO2 to formate, achieving a TON of 58,530. Notably, the ImA-1 catalyst also efficiently produces formate from bicarbonate.
Zirconium Oxychloride Hydrate: An Efficient and Reusable Catalyst for Retro-Claisen Condensation of Alcohols with 1,3-Diketones Supriyo Majumder, Durgaiah Chevella and Chiranjeevi Thota Abstract Esters are one of the most versatile and fundamental class of compounds with tremendous industrial demand. They are generally synthesized via the condensation of alcohol with acid.
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