Thiadiazolo[3,4-c]pyridine (PT) has great potential in constructing high-performance narrow bandgap (NBG) photovoltaic polymers. But to date the best power conversion efficiencies (PCEs) for PT-containing polymers are only around 6%. Herein we report two PT-containing NBG polymers PDTPT-2T and PDTPT-2TF based on 2,2'-bithiophene (2T) and 3,3'-difluoro-2,2'-bithiophene (2TF), respectively. The effects of fluorine substituent on optoelectronic properties are thoroughly investigated.