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Biocatalytic reductive aminations with NAD(P)H-dependent enzymes: enzyme discovery, engineering and synthetic applications† Chiral amines are pivotal building blocks for the pharmaceutical industry. Asymmetric reductive amination is one of the most efficient and atom economic methodologies for the synthesis of optically active amines.
In recent decades, biocatalysis has attracted more and more attention, contributing significantly to synthetic organic chemistry and biotechnology, and thereby advancing the development of greener and more sustainable synthetic processes. As a versatile enzyme, carboxylic acid reductases (CARs) are widely distributed in bacteria, fungi and plants.
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