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A solution-processable double-cable polymer (PFT-PDI), composed of the backbone poly(fluorene-alt-thiophene) (PFT), the n-butoxyl linker, and the pendants perylenediimides (PDI), was developed. PFT-PDI was almost nonconductive with the hole and electron mobilities in the order of 10–10. There was no charge transfer but energy transfer from the donor PFT chain to the acceptor PDI units.
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