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Download Hi-Res ImageDownload to MS-PowerPointCite This:Organometallics 2023, XXXX, XXX Mirela A. Farcaş-Johnson Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom School of Chemistry, Faculty of Science, University of New South Wales, Sydney, NSW 2052, Australia , Danila Gasperini Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom , Andrew K.
Download Hi-Res ImageDownload to MS-PowerPointCite This:Organometallics 2021, XXXX, XXX Nathan T. Coles, Danila Gasperini Danila Gasperini Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom , Cei B. Provis-Evans, Mary F. Mahon Mary F. Mahon Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom , and Ruth L.
Abstract Transfer hydrogenation (TH) has historically been dominated by Meerwein–Ponndorf–Verley (MPV) reactions. However, with growing interest in amine–boranes, not least ammonia–borane (H3N⋅BH3), as potential hydrogen storage materials, these compounds have also started to emerge as an alternative reagent in TH reactions. In this Review we discuss TH chemistry using H3N⋅BH3 and their analogues (amine–boranes and metal amidoboranes) as sacrificial hydrogen donors.
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