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The equilibrium solubility of the quaternary system Na+, NH +//SO 2–, NO ––H O at 303.15 and 323.15 K was determined by an isothermal dissolution equilibrium method. The weighing bottle method and Abbe refractometer were adopted to measure the density and refractive index of the aqueous liquid phase. The solid-phase invariant points at equilibrium were confirmed by X-ray diffractometry.
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