Realizing long range π-conjugation in phenanthrene and phenanthrene-based molecular crystals for anomalous piezoluminescence† Unlike the known aggregation-caused quenching (ACQ) that the enhancement of π–π interactions in rigid organic molecules usually decreases the luminescent emission, here we show that an intermolecular “head-to-head” π–π interaction in the phenanthrene crystal, forming the so-called “transannular effect”, could result in a higher degree of electron delocalization and...