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Sulfur (VI)-doped Ba2In2O5+δ was synthesised by solid state reaction. A stabilised orthorhombic perovskite could be achieved at low-temperature by the introduction of a sulfur content of x=0.2 in Ba2In2-xSxO5+δ. The mixed (electronic-protonic-oxide-ionic) conducting properties of this composition were investigated in detail for potential interest in a wide range of membrane applications including Protonic Ceramic Fuel Cells.
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