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Articles by Eric Hope
Ligand and solvent control of selectivity in the C-H activation of a pyridylimine-substituted 1-naphthalene; a combined synthetic and computational study
The pyridylimine-substituted 1-naphthalenes, 2-(1-C10H7)-6-{CR=N(2,6-i-Pr2C6H3)}C5H3N (R = Me HLMe, H HLH), react with Na2[PdCl4] in acetic acid at elevated temperature to afford either ortho-C-Hnaphthyl activated (LMe)PdCl (2ortho) or the unactivated adduct (HLH)PdCl2 (1b). Alternatively, 1b and its ketimine analogue (HLMe)PdCl2 (1a), can be prepared by treating (MeCN)2PdCl2 with either HLMe or HLH in chloroform at room temperature.
East City Artnotes: Art of Engagement at Touchstone Gallery
The Art of Engagement is Touchstone Gallery’s second foray into the world of politics and presents a more angst-ridden take on today’s political climate than last August’s Art as Politics show (see that review here). Underscoring how elections have consequences, juror Jack Rasmussen has selected over 70 artists that give voice to the grave concerns of the political left.
East City Artnotes: Artina 2017 at the Sandy Spring Museum
Artina2017: (Re)Use and Abuse of the Land is the second partnership between the Sandy Spring Museum and Washington Sculptors Group. The seventeen sculptures situated throughout the bucolic acreage surrounding the museum’s main building and artist studios attempt to reinforce the notion that nature is at its core a series of overlapping biological systems, our human existence being only one piece of this complex puzzle.
East City Artnotes: The Art of Allen Hirsh at Foundry Gallery
Allen Hirsh’s current exhibition on display at Foundry Gallery in Shaw is an unusual juxtaposition of science and beauty. Armed with a PhD in biophysics, the artist views the natural world through a mathematical filter, transforming prosaic still-life scenes (think flowers, building facades) into multilayered abstractions endowed with a sense of fluid motion.
How the Civil War Changed Visual Communication
The sesquicentennial of the Civil War’s end brings renewed interest and scholarship to a seminal point in American History. The Smithsonian Anacostia Community Museum highlights that interest with a new exhibition examining the war’s impact on the District and its residents. How the Civil War Changed Washington (on view through November 15, 2015) is unique for two reasons.
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