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Articles by Eszter Borbas
Synthesis of oligosaccharides and conformational analysis by NMR spectroscopy
Nyckelord: NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Sammanfattning: The first part of this thesis describes investigations of the conformations of six N-linked pseudodisaccharides (Paper I), which were synthesized as glycosidase inhibitor candidates, and 10 β-D-xylopyranoside derivatives bearing hydrophobic aglycons (Paper II), by NMR spectroscopic methods.
Photochemical generation of divalent lanthanides : Applications in organic synthesis and small molecule activation
Nyckelord: NATURVETENSKAP; NATURAL SCIENCES; lanthanide; photoinduced electron transfer; chromophore; photocatalysis; Kemi med inriktning mot organisk kemi; Chemistry with specialization in Organic Chemistry; Sammanfattning: Trivalent lanthanide (Ln(III)) compounds are known for their luminescent properties. Luminescence sensitization often happens via the so-called "antenna effect": a light-harvesting chromophore which transfers its excitation energy to Ln(III) ions.
Tuning the photophysical properties of luminescent lanthanide complexes through regioselective antenna fluorination
Tuning the photophysical properties of luminescent lanthanide complexes through regioselective antenna fluorination Daniel Kocsi, Andreas Orthaber and Eszter Borbas Abstract Carbostyrils monofluorinated in the 3, 5, or 6 positions were synthesised from olefinic precursors via a photochemical isomerisation-cyclisation route, and incorporated into octadentate cyclen triacetate ligands that formed luminescent complexes with Tb(III) and Eu(III).
Reduced quenching effect of pyridine ligands in highly luminescent Ln(III) complexes: the role of tertiary amide linkers
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Electron transfer pathways in photoexcited lanthanide(III) complexes of picolinate ligands
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Highly luminescent lanthanide complexes sensitised by tertiary amide-linked carbostyril antennae
Carbostyrils are among the most widely used sensitising antennae for luminescent lanthanides; they afford bright complexes with Eu and Tb, and can also sensitise the emissions of the less commonly used Sm, Dy, Yb and Nd. Systematic studies on the effect of structural variations on the photophysical properties and lanthanide sensitising abilities of carbostyrils can therefore have a large impact.
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