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Brønsted acid catalysis opens a new route to polythiolesters via the direct condensation of thiolactic acid to thiolactide† An Sofie Narmon, ab Evelien Leys,a Ibrahim Khalil, a Gleb Ivanushkin a and Michiel Dusselier *a Abstract Polythiolesters (PTEs) are a rather underinvestigated group of sulfur-containing polymers with high potential as sustainable materials due to their enhanced de-polymerizability under specific conditions compared to polyesters (PEs).
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