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Abstract High-resolution photoelectron spectra of xenon (Xe) were measured in the 4p photoionization region. The anisotropy parameters β were obtained for several photoelectron peaks with angle-resolved photoelectron measurements. The various complicated spectral features were observed due to the perturbed 4p−1 spin-orbit doublet and adjacent satellite structures. An analysis based on a relativistic multiconfiguration calculation has been carried out.
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