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Articles by Fabiano Visentin
Liposomal Formulations of Metallodrugs for Cancer Therapy
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Antibody Drug Conjugates for Cancer Therapy: From Metallodrugs to Nature-Inspired Payloads
All articles published by MDPI are made immediately available worldwide under an open access license. No special permission is required to reuse all or part of the article published by MDPI, including figures and tables. For articles published under an open access Creative Common CC BY license, any part of the article may be reused without permission provided that the original article is clearly cited. For more information, please refer to https://www.mdpi.com/openaccess.
Reactivity of Palladium(II)-η3-Allyl Complexes with Chalcogenolates: A Density Functional Study of Their Antitumor Implications
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Recent Advances in Bioconjugated Transition Metal Complexes for Cancer Therapy
This is an early access version, the complete PDF, HTML, and XML versions will be available soon. Open AccessReview by 1, 1 and 2,* 1 Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari, Campus Scientifico Via Torino 155, 30174 Venezia-Mestre, Italy 2 Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131 Padova, Italy * Author to whom correspondence should be addressed. Appl. Sci.
Measuring the olefin‐to‐Pd(0) bond strength: a kinetic study involving olefin exchange reactions on palladium(0) complexes bearing isocyanide ligands.
Full Paper Fabiano Visentin Corresponding Author E-mail address: fvise@unive.it Universita Ca' Foscari, Scienze Molecolari e Nanosistemi, via Torino 155, 30172 Mestre, ITALY Search for more papers by this author PDF ShareShare Abstract In this paper we describe the synthesis and characterization of new palladium(η 2 ‐olefin) complexes bearing isocyanides as spectator ligands.
A critical review of palladium organometallic anticancer agents
Summary With the aim of overcoming the well-known limitations of platinum-based antineoplastic drugs, recent efforts have focused on the development of new anticancer agents containing metals other than platinum. Among these agents, organopalladium compounds have received significant recent attention due to their generally high stability under physiological conditions.
Reactivity of N-heterocyclic carbene-pyridine palladacyclopentadiene complexes toward halogens addition. The unpredictable course of the reaction
As an extension of a previously published work we have reacted some palladacyclopentadiene complexes stabilized by bidentate N-heterocyclic carbene-pyridine or monodentate N-heterocyclic carbene-pyridine and isocyanide ligands with the halogens I2 and Br2. All the bidentate and monodentate complexes react with halogens to give at first the expected ?-coordinated butadienyl fragment.
The isocyanide insertion across the Pd-C bond of allenyl and propargyl palladium complexes bearing phosphoquinoline as spectator ligand. The synthesis of a palladium complex bearing a coordinated cyclobutenyl fragment. - Dalton Transactions (RSC Publishin
We have studied the insertion of p-toluensulfonylmethyl isocyanide (TosMIC) on selected allenyl and propargyl complexes of palladium bearing diphenylphosphine quinoline as spectator ligand. The fast process gives different products depending on the tautomer involved in the reaction. Thus, the unsubstituted allenyl species yields the insertion complex with the isocyanide coordinated between the metal and the first allenyl carbon.
The unexpected case of reactions of halogens and interhalogens with halide substituted Pd(
We have experimentally studied and theoretically interpreted the addition under stoichiometric conditions of halogens or interhalogens to σ-butadienyl palladium complexes bearing the heteroditopic thioquinolines as spectator ligands. The observed reactions do not involve the expected extrusion of the butadienyl fragment but rather the unpredictable substitution of the halide coordinated to palladium and in some cases also of that bound to the terminal butadienyl carbon.
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