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Selective Ethylene Tetramerization: An Overview Biao-Biao Hao, Fakhre Alam, Yan Jiang, Libo Wang, Haonan Fan, Ma Jing, Yanhui Chen, Yating Wang and Tao Jiang Abstract With greater market demand, interest in the selective production of linear α-olefins has been increasing.
High performance catalysts switched by a series of silicon-bridged/N, P-based ancillary ligands have been explored. The precatalyst supported by L1 possessed a large steric bulk and exhibited a high activity of 16.8×10 g/(mol ?h) as well as a 99% total selectivity toward 1-hexene and 1-octene. The selectivity of 1-hexene was adjustable from 59% to 88%.
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