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Desymmetric hydrolysis of prochiral imide for S-pregabalin synthesis by rationally designed d-hydantoinase† Feixia Liu,‡a Jie Ren,‡b Lu Guo,c Yang Liu,ad De-Feng Li c and Bo Yu *a Abstract S-Pregabalin (S-PGB) is an effective medicine for analgesic, anticonvulsant and anxiolytic treatments. To date, enantioselective synthesis of S-PGB suffers from 50% undesired by-product that needs to be recycled via highly polluting chemical processes.
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