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Articles by Filippo Romiti
Diastereo- and enantioselective synthesis of compounds with a trifluoromethyl- and fluoro-substituted carbon centre - Nature Chemistry
Abstract Molecules that contain one or more fluorine atoms are crucial to drug discovery. There are protocols available for the selective synthesis of different organofluorine compounds, including those with a fluoro-substituted or a trifluoromethyl-substituted stereogenic carbon centre. However, approaches for synthesizing compounds with a trifluoromethyl- and fluoro-substituent stereogenic carbon centre are far less common.
Streamlined Catalytic Enantioselective Synthesis of α-Substituted β,γ-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers
A widely applicable, practical, and scalable strategy for efficient and enantioselective synthesis of β,γ-unsaturated ketones that contain an α-stereogenic center is disclosed.
A Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing a Z-Alkenyl Chloride or Trifluoromethyl Group. A Concise and Protecting Group-Free Synthesis of Mycothiazole
A protecting group-free strategy is presented for diastereo- and enantioselective routes that can be used to prepare a wide variety of Z-homoallylic alcohols with significantly higher efficiency than is otherwise feasible. The approach entails the merger of several catalytic processes and is expected to facilitate the preparation of bioactive organic molecules.
Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2019, XXXX, XXX RETURN TO ARTICLES ASAPPREVPerspectiveNEXT Filippo Romiti Filippo Romiti Supramolecular Science and Engineering Institute, University of Strasbourg, CNRS, 67000 Strasbourg, France Juan del Pozo Juan del Pozo Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States Paulo H. S. Paioti Paulo H. S.
Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems
An emerging area of research in chemistry requires that we learn how to manage the characteristics of a pair of co-catalysts so that a transformation proceeds as we wish it to. These are processes during which one catalyst first generates a non-isolable intermediate, which then in situ undergoes a reaction that is promoted by a different catalyst. This scenario raises several design issues.
Frontispiece: Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives
Frontispiece Frontispiece: Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives Prof. Dr. Amir H.
Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F‐Substituted Stereogenic Quaternary Center - Akiyama - - Angewandte Chemie International Edition - Wiley Online Library
Communication Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F‐Substituted Stereogenic Quaternary Center Hajime Ito Corresponding Author E-mail address: hajito@eng.hokudai.ac.jp Hokkaido University, Division of Chemical Process Engineering, Kita-13 Nishi-8, Kita-ku, 060-8628 Sapporo, JAPAN Search for more papers by this author PDF PDF Share Abstract The first catalytic method for diastereo‐ and...
Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F‐Substituted Stereogenic Quaternary Center - Akiyama - - Angewandte Chemie International Edition - Wiley Online Library
Communication Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F‐Substituted Stereogenic Quaternary Center Hajime Ito Corresponding Author E-mail address: hajito@eng.hokudai.ac.jp Hokkaido University, Division of Chemical Process Engineering, Kita-13 Nishi-8, Kita-ku, 060-8628 Sapporo, JAPAN Search for more papers by this author PDF PDF Share Abstract The first catalytic method for diastereo‐ and...
Delayed catalyst function enables direct enantioselective conversion of nitriles to NH2-amines
Research Article Shaochen Zhang1,*, Juan del Pozo1,*, Filippo Romiti1,2,*, Yucheng Mu1, Sebastian Torker1,2, Amir H. Hoveyda1,2,† 1Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA. 2Supramolecular Science and Engineering Institute, University of Strasbourg, 67000 Strasbourg, France. ↵†Corresponding author. Email: amir.hoveyda{at}bc.edu or ahoveyda{at}unistra.fr ↵* These authors contributed equally to this work.
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