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A novel N5-linear energetic moiety of pentazadiene has been constructed for the first time from triazene precursor. Thus, a series of 1,3,5-tri(tetrazol-5-yl)pentaza-1,4-dienes have been syn-thesized in moderate to high yield by treatment of 1,3-bis(tetr-azol-5-yl)triazenes with 1-(3-dimethylaminopropyl)-3-ethylcar-bodiimide hydrochloride (EDCI) under mild conditions.
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