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Alkyl-templated cocrystallization of long-chain 1-bromoalkanes by lipid-like ionic liquids† The serendipitous discovery of an unorthodox ionic cocrystallization system using 2-mercaptothiazolium-based ionic liquids as a crystallization milieu paves the way for the first report of crystal structures of long-chain 1-bromoalkanes.
Deep eutectic solvents (DESs) were first introduced by Abbott in 2004, a leading innovator in the field, who reported that mixing a high melting organic salt, a hydrogen bond acceptor (HBA), and a neutral organic molecule, a hydrogen bond donor (HBD), in appropriate molar ratio results in a mixture that is a liquid at room temperature.1,21. A. P. Abbott, D. Boothby, G. Capper, D. L. Davies, and R. K.
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