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Articles by Gregor Kieslich
Alkali-ion-modified zeolitic imidazolate framework glasses
Abstract Modifying glass compositions is key to creating silicate-based glasses for technologies including optical fibres, catalytic supports, protective coatings and separation membranes. Here we extend this concept to metal–organic framework (MOF) glasses by modifying the MOF glass former ZIF-62 with Li(bim) and Na(bim) as compatible glass modifiers (benzimidazolate, bim−).
Elucidating the Solubility Enhancement of Active Pharmaceutical Ingredients through Hydrotropy: A Case of Local Anesthetics
1. Introduction Click to copy section linkSection link copied! The development and design of new pharmaceutical drugs require understanding the solubility of active pharmaceutical ingredients (APIs) when combined with excipients. Excipients are inert substances added to APIs to improve their long-term stability, solubility, bioavailability, and therapeutic efficacy.
Elucidating the Solubility Enhancement of Active Pharmaceutical Ingredients through Hydrotropy: A Case of Local Anesthetics
1. Introduction Click to copy section linkSection link copied! The development and design of new pharmaceutical drugs require understanding the solubility of active pharmaceutical ingredients (APIs) when combined with excipients. Excipients are inert substances added to APIs to improve their long-term stability, solubility, bioavailability, and therapeutic efficacy.
The Wondrous World of ABX3 Molecular Perovskites
The Wondrous World of ABX3 Molecular Perovskites The substitution of atoms with molecular building blocks to form hybrid organic-inorganic networks has been an important research theme for several decades. ABX3 Molecular Perovskites (MolPs) are a subclass of hybrid networks, adopting the perovskite structure with cationic and anionic molecules on the A-site and X-site.
Structural flexibility in crystalline coordination polymers: a journey along the underlying free energy landscape
Structural flexibility in crystalline coordination polymers: a journey along the underlying free energy landscape Crystalline coordination polymers are a chemically diverse material platform that provide control over network geometry and chemical interactions, harbouring a wealth of phenomena of large scientific and technological relevance.
Understanding the Balance of Entropy and Enthalpy in Hydrogen-Halide Noncovalent Bonding
Hydrogen bonds are of great scientific interest, determining the free energy landscape and hence chemical and physical properties of many materials systems, for example, the hybrid organic–inorganic perovskites. Although these interactions are critical, understanding them is difficult in complex, multicomponent systems; hydrogen halides are ideal as simple binary model compounds for understanding the role of hydrogen bonding in physical properties like phase transitions.
Tolerance Factors of hybrid perovskites: recent improvements and current state of research
In 2014 we have applied Goldschmidt’s concept of ionic Tolerance Factors to organic-inorganic perovskites, highlighting the large opportunities that come with the compositional flexibility of the perovskite structure motif combined with the large library of molecular A-cations. Since our initial report there have been many research examples in which Tolerance Factors were used to synthesise new materials while the concept itself has been constantly improved.
Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH3NH2]1-x[NH3OH]xZn(HCOO)3
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