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In this work, we report a novel design of mixed P2+T phase NaxCo0.1Mn0.9O2(0.44≤x≤0.7) with interface rich characteristic for high performance sodium storage, whereby the tunneled T phase offers fast Na ion diffusivity and excellent structural stability, the layered P2 phase contributes high specific capacity, and the P2-T phase interface offers additional channels and active sites for charge transfer and excess charge storage.
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