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Articles by Hanbyul Kim
Condensed Matter > Materials Science
Interlayer coupling controls the electronic properties of layered van der Waals transition metal dichalcogenides. We investigate light-induced control of the interlayer spacing through orbital-selective excitation in trilayer 1T'-WSe2 and 1T'-WS2. Real-time time-dependent density functional theory simulations show that the interlayer spacing contracts or expands depending on whether chalcogen p-orbital density is depleted from or accumulated in the interlayer region.
Linearly polarized light-induced magnetism in bilayer MoSe₂
Abstract Light-induced symmetry breaking offers a powerful route to manipulate material properties by driving them into non-equilibrium states. Here, we demonstrate that a linearly polarized light transiently breaks time-reversal symmetry in bilayer MoSe2, a nominally non-magnetic van der Waals system. Combined ultrafast measurements and first-principles simulations reveal that linearly polarized excitation launches interlayer-coupled coherent phonons through a displacive mechanism.
Revised Mechanism of Gold-Catalyzed Thioallylation of Propiolates
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Org. Chem. 2023, XXXX, XXX Terms & Conditions Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses).
Gold-Catalyzed Asymmetric Thioallylation of Propiolates via Charge-Induced Thio-Claisen Rearrangement
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc.
Synthesis of γ-substituted carbonyl compounds from DMSO-mediated oxidation of enynamides: mechanistic insights and carbon- and hetero-functionalizations
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Asymmetric Synthesis of Dihydropyranones via Gold(I)‐Catalyzed Intermolecular [4+2] Annulation of Propiolates and Alkenes
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
Asymmetric Synthesis of Dihydropyranones via Au(I)‐Catalyzed Intermolecular [4+2] Annulation of Propiolates and Alkenes
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
Fragile skin microbiomes in megacities are assembled by a predominantly niche-based process
Given the higher incidence of skin diseases in more urbanized populations and its association with the skin microbiome, we questioned how the skin microbiome differed depending on the degree of urbanization. Skin microbiomes of 231 healthy subjects in five large cities in China varied mainly with environment and socioeconomic status of the cities in question.
Fragile skin microbiomes in megacities are assembled by a predominantly niche-based process
Given the higher incidence of skin diseases in more urbanized populations and its association with the skin microbiome, we questioned how the skin microbiome differed depending on the degree of urbanization. Skin microbiomes of 231 healthy subjects in five large cities in China varied mainly with environment and socioeconomic status of the cities in question.
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