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Hanna Busch

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Articles by Hanna Busch

Hydroxynitrile lyases covalently immobilized in continuous flow microreactors

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By Afdeling Biotechnologie, Technische Universiteit Delft, Hanna Busch, Paula Bracco
| Royal Society of Chemistry Verified
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Growth Kinetics of Stacks of Lamellar Polymer Crystals

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By Sumit Datt Majumder, Hanna Busch, Purushottam Poudel, Stefan Mecking
| American Chemical Society
Most theoretical concepts of polymer crystallization have evolved around monolamellar single crystals as model systems. However, such approaches do not account for an important and unique aspect of crystallization of long flexible molecules: the correlated stacking of lamellar crystals. In our experimental work, we focus on the growth kinetics of such stacks of lamellae in thin films of poly(nonadecane methylphosphonate).
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Ultralong-Chain-Spaced Crystalline Poly(H-phosphonate)s and Poly(phenylphosphonate)s

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By Hanna Busch, Stefan Mecking, Eva Schiebel, Annika Sickinger
| American Chemical Society
Aliphatic poly(H-phosphonate)s were obtained by polyesterification of dimethyl H-phosphonate with bio-based long-chain diols. Nonadecane-1,19-diol, tricosane-1,23-diol, and octatetracontane-1,48-diol with dimethyl H-phosphonate yield the corresponding polyphosphoesters (PPE19H, PPE23H, and PPE48H) with molecular weights (M ) up to 4.3 × 104 g mol–1.
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Semicrystalline Long-Chain Polyphosphoesters from Polyesterification

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By Sumit Datt Majumder, Stefan Mecking, Hanna Busch, Günter Reiter
| American Chemical Society
Semicrystalline aliphatic polyphosphoesters can be obtained in a one-step approach by polyesterification of readily available bio-based long-chain diols with dichlorophosphorus compounds. Nonadecane-1,19-diol and tricosane-1,23-diol with respectively methylphosphonic dichloride or phenyl dichlorophosphate yield polymers (PPE19Me, PPE23Me, PPE19(OPh), and PPE23(OPh)) with molecular weights M up to 3 × 104 g mol–1.
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