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1 Introduction The Daphniphyllum alkaloids1a-1j constitute an extraordinarily unique and structurally sophisticated class of natural products. Taming structural diversity, daphniphyllum alkaloids are often classified according to signature structural motifs and the proposed biosynthesis. The polycyclic, cage-like daphnicyclidine alkaloids form a particularly fascinating branch within the Daphniphyllum alkaloid family.
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