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Articles by Jana Weßing
Cover Picture: The Mackay‐Type Cluster [Cu43Al12](Cp*)12: Open‐Shell 67‐Electron Superatom with Emerging Metal‐Like Electronic Structure (Angew. Chem. Int. Ed. 44/2018) - Weßing - 2018 - Angewandte Chemie International Edition - Wiley Online Library
The M magic‐atom‐number cluster [Cu Al ](Cp*) features a Mackay‐type nested icosahedral core–shell structure, protected by twelve Cp* (Cp*=η‐C (CH ) ) groups. As shown by J.‐Y. Saillard, R. A. Fischer, and co‐workers in their Communication on page 14630 ff., its open‐shell 67 electron superatom configuration features three unpaired electrons occupying weakly antibonding jellium states.
The Mackay‐Type Cluster [Cu43Al12](Cp*)12: Open‐Shell 67‐Electron Superatom with Emerging Metal‐Like Electronic Structure
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
Cover Picture: The Mackay‐Type Cluster [Cu43Al12](Cp*)12: Open‐Shell 67‐Electron Superatom with Emerging Metal‐Like Electronic Structure (Angew. Chem. Int. Ed. 44/2018) - Weßing - 2018 - Angewandte Chemie International Edition - Wiley Online Library
The M magic‐atom‐number cluster [Cu Al ](Cp*) features a Mackay‐type nested icosahedral core–shell structure, protected by twelve Cp* (Cp*=η‐C (CH ) ) groups. As shown by J.‐Y. Saillard, R. A. Fischer, and co‐workers in their Communication on page 14630 ff., its open‐shell 67 electron superatom configuration features three unpaired electrons occupying weakly antibonding jellium states.
The Mackay‐Type Cluster [Cu43Al12](Cp*)12: Open‐Shell 67 Electron Superatom with Emerging Metal‐Like Electronic Structure
The M magic‐atom‐number cluster [Cu Al ](Cp*) features a Mackay‐type nested icosahedral core‐shell structure, protected by twelve η‐C (CH ) groups (Cp*). As shown by J.‐Y. Saillard, R. A. Fischer, and co‐workers in their Communication (DOI: 10.1002/anie.201806039), its open‐shell 67 electron superatom configuration features three unpaired electrons occupying weakly antibonding jellium states.
Intermetalloid Clusters: Molecules and Solids in a Dialogue
Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model systems to study fundamental structure and bonding situations of compositionally related molecules and extended solid phases. However, this fascinating field of research is still largely restricted to homometallic and pseudo‐heterometallic systems of closely related d‐block metals.
Intermetalloid Clusters: Molecules and Solids in a Dialogue
Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model systems to study fundamental structure and bonding situations of compositionally related molecules and extended solid phases. However, this fascinating field of research is still largely restricted to homometallic and pseudo‐heterometallic systems of closely related d‐block metals.
Intermetalloid Clusters: Molecules and Solids in a Dialogue
Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model systems to study fundamental structure and bonding situations of compositionally related extended solid phases. However, this fascinating field of research is still largely restricted to homometallic and pseudo‐heterometallic systems of closely related d‐block metals.
The Mackay‐Type Cluster [Cu43Al12](Cp*)12: Open‐Shell 67‐Electron Superatom with Emerging Metal‐Like Electronic Structure
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
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