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Heterotrimetallic {LnOVPt} complexes with antiferromagnetic Ln–V coupling and magnetic memory† Stephanie A. Beach, a Jesse L. Guillet,a Sydney P. Lagueux,a Mauro Perfetti, b Brooke N. Livesay, c Matthew P. Shores, c Jeffrey W. Bacon, a Arnold L. Rheingold, d Polly L. Arnold ‡§e and Linda H.
Four new quasi-1D Ni -lantern chain complexes of the form [Ni (SOCR) (L)] (R = Ph, L = DABCO (1); R = Ph, L = pyz (2); R = CH , L = DABCO (3); R = CH , L = pyz (4)) were prepared from the reaction of [Ni (SOCR) (EtOH)], R = CH or Ph, with the N,N?-donor bridging ligands pyrazine (pyz) or 1,4-diazabicyclo[2.2.2]octane (DABCO).
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