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Abstract To investigate the effect of nanofiller dimensionality on the thermal stability of poly(m-phenylene isophthalamide) (PMIA) insulating films and the underlying mechanisms, zero-dimensional ZrO₂ nanoparticles and two-dimensional fluorinated graphene (FG) were selected as representative fillers. Molecular dynamics simulations were performed on neat PMIA, ZrO₂/PMIA, and FG/PMIA nanocomposites with different filler loadings.
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