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Abstract Steady-state and time-resolved cryogenic ion spectroscopy of TrpH+−H2O reveal that a single water molecule, inserted in between the ammonium and indole groups, blocks the excited-state proton transfer occurring in protonated tryptophan. Abstract The photodynamics of protonated tryptophan and its mono hydrated complex TrpH+−H2O has been revisited.
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