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Highly Regio- and Diastereoselective (3 + 3)-Cycloannulation of Carbonyl Ylides and 2‑(1-Alkynyl)-2-alken-1-ones Enabled by Silver Catalysis A highly regio- and diastereoselective (3 + 3)-cycloannulation of in situ generated carbonyl ylides and 2‑(1-alkynyl)-2-alken-1-ones enabled by silver catalysis is reported. This work is the first to describe a silver catalysed synthesis of 3,4-fused furan with an oxa-bridged motif.
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