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Articles by Kaeden Teindl
Highly Acidic Second Coordination Spheres Promote In Situ Formation of Iron Phlorins Exhibiting Fast and Selective CO2 Reduction
Cite Jump to ExpandCollapse ArticleJanuary 2, 2026 Highly Acidic Second Coordination Spheres Promote In Situ Formation of Iron Phlorins Exhibiting Fast and Selective CO2 Reduction Click to copy article linkArticle link copied! Kaeden Teindl Kaeden Teindl Department of Chemistry, The University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada Daniel Jacobs Daniel Jacobs Department of Chemistry, State University of New York at Binghamton, Binghamton, New York 13902, United...
Electrochemical Formation of Methane, Ethylene, and Ethane with a Bimetallic Nickel Complex: Is CO2 the Source of Carbon?
Electrochemical Formation of Methane, Ethylene, and Ethane with a Bimetallic Nickel Complex: Is CO2 the Source of Carbon? Most molecular CO2 reduction electrocatalysts generate CO as the only gaseous carbon product. Herein, we report a dinickel complex that produces H2, CO, CH4, C2H4, and C2H6 under negative applied potentials. Using 13C isotopic labeling and high-resolution mass spectrometry, we find that CO and CH4 originate from CO2, C2H4 does not, and the origin of C2H6 remains unresolved.
Linear Free Energy Relationships and Transition State Analysis of CO2 Reduction Catalysts Bearing Second Coordination Spheres with Tunable Acidity
In molecular catalysts, protic functional groups in the secondary coordination sphere (SCS) work in conjunction with an exogenous acid to relay protons to the active site of electrochemical CO2 reduction; however, it is not well understood how the acidity of the SCS and exogenous acid together determine the kinetics of catalytic turnover.
NiII and CuII complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere
NiII and CuII complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere† Rachel Sailer,a Warren VandeVen, b Kaeden Teindl‡a and Linus Chiang *a Abstract Herein, we report the synthesis, spectroscopic characterization and electrochemical investigation of the NiII and CuII complexes of a novel Sal ligand bearing two ferrocene moieties attached at its diimine linker, M(Sal)Fc. The electronic spectra of M(Sal)Fc are near identical to its phenyl-substituted counterpart,...
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