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Articles by Laia Davin
Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air
Communication Dr. Joaquín García‐Álvarez Corresponding Author E-mail address: garciajoaquin@uniovi.es Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Departamento de Química Orgánica e Inorgánica (IUQOEM), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Química, Universidad de Oviedo, 33071 Oviedo, Spain Search for more papers by this author Prof.
s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols
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Alkali Metal and Stoichiometric Effects in Intermolecular Hydroamination Catalysed by Lithium, Sodium and Potassium Magnesiates
Alkali Metal and Stoichiometric Effects in Intermolecular Hydroamination Catalysed by Lithium, Sodium and Potassium Magnesiates Main group bimetallic complexes, while being increasingly used in stoichiometric deprotonation and metal-halogen exchange reactions, have largely been overlooked in catalytic applications.
Magnesium-Mediated Arylation of Amines via C-F Bond Activation of Fluoroarenes
Magnesium-Mediated Arylation of Amines via C-F Bond Activation of Fluoroarenes A series of new Mg(II) amides featuring a bulky β-diketiminate backstop ligand, has been synthesised. These complexes are demonstrated to be excellent sources of nucleophilic amides that can participate in rapid C-F activation of several fluoroarenes at room temperature or using microwave assistance, leading to the installment of synthetically important C-N bonds via nucleophilic substitution.
Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations
Using ?-diketiminate Mg(II) complexes containing either alkyl, aryl or amide groups, the regioselective functionalization of a wide range of fluoroarenes is accomplished but in uniquely different ways.
Regioselective magnesiation of N-heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp
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