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Download Hi-Res ImageDownload to MS-PowerPointCite This:Crystal Growth & Design 2024, XXXX, XXX CCDC 2322701–2322711 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, U.K.; fax: +44 1223 336033.
Switching from positive to negative axial thermal expasion in pure organic materials is reported for the first time. The rare phenomenon has been rationalized based on packing of molecules in crystal structures and tranverse thermal vibration of atoms in the molecule. Unique packing of the molecules in the crystal structure contributes to the restricted movement of molecules along c axis.
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