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Sequential acid-catalyzed alkyl glycosylation and oligomerization of unprotected carbohydrates An efficient method has been developed to synthesize end-functionalized oligosaccharides from unprotected monosaccharides in a one-pot/two-step approach. In the first step, mannose (and glucose) were functionalized with an alkyne group at the anomeric position through Fisher-glycosylation reaction with propargyl alcohol as glycosyl acceptor.
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