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Coinage metal complexes of multidentate Pacman phosphane ligands† Leon Ohms, a Liesa Eickhoff, a Pascal Kramer, a Alexander Villinger, a Jonas Bresien a and Axel Schulz *ab Abstract We present the extension of Pacman ligands to bidentate phosphane ligands enabling them to bind metals in their sterically protected cavity.
Abstract The reactivity of the four‐membered NP3 ring system [RN(μ‐PCl)2PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature‐known, analogous cyclic compounds [ClP(μ‐NR)]2 (R=Ter=2,6‐dimesitylphenyl) and [ClP(μ‐PR)]2 (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species.
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