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Articles by Linjun Qi
Hydrazine-mediated carbonyl–alkyne/allene reductive olefination
Abstract Cycloolefin is a privileged motif with significant implications across multiple disciplines. While cycloolefination represents the most unified disconnection strategy, the corresponding approaches are notably scarce. Here we report a hydrazine-mediated carbonyl–alkyne reductive olefination (CARO), offering a minimalist approach to structurally complex cycloolefins. This CARO protocol is also applicable to carbonyl–allene and lactol–alkyne analogues.
Divergent Synthesis of α,β -Unsaturated γ-Lactams via Tunable C–H Annulation of Acrylic Acids with Imines Click to copy article link Article link copied!
Cite Jump to ExpandCollapse LetterMarch 20, 2026 Divergent Synthesis of α,β-Unsaturated γ-Lactams via Tunable C–H Annulation of Acrylic Acids with Imines Click to copy article linkArticle link copied! Xin Zhang Xin Zhang School of Pharmaceutical and Chemical Engineering & Institute for Advanced Studies, Taizhou University, Taizhou, Zhejiang 318000, China Linjun Qi Linjun Qi School of Pharmaceutical and Chemical Engineering & Institute for Advanced Studies, Taizhou University, Taizhou,...
Ru-Catalyzed Switchable Reactions of Acrylic Acids with Glyoxylate: Access to Functionalized γ-Butenolides
Organic Letters Cite this: Org. Lett. 2024, XXXX, XXX Click to copy citationCitation copied! Learn about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days. Citations are the number of other articles citing this article, calculated by Crossref and updated daily.
Palladium-Catalyzed Heck/Suzuki Tandem Reaction of (Z)-1-Iodo-1,6-dienes and Organoboronic Acids
The Heck/Suzuki tandem reaction has emerged as an essential strategy for the synthesis of complex molecules. Herein, an efficient palladium-catalyzed Heck/Suzuki tandem reaction of (Z)-1-iodo-1,6-dienes with organoboronic acids is described, providing various tetrahydropyridines in good to excellent yields under mild reaction conditions. The key to the success of this approach is the avoidance of the intramolecular second Heck insertion occurring prior to the transmetalation step.
Palladium-Catalyzed Heck/Suzuki Tandem Reaction of (Z)-1-Iodo-1,6-dienes and Organoboronic Acids
The Heck/Suzuki tandem reaction has emerged as an essential strategy for the synthesis of complex molecules. Herein, an efficient palladium-catalyzed Heck/Suzuki tandem reaction of (Z)-1-iodo-1,6-dienes with organoboronic acids is described, providing various tetrahydropyridines in good to excellent yields under mild reaction conditions. The key to the success of this approach is the avoidance of the intramolecular second Heck insertion occurring prior to the transmetalation step.
Pd0‐Catalyzed Asymmetric Carbonitratation Reaction Featuring an H‐Bonding‐Driven Alkyl−PdII−ONO2 Reductive Elimination
Research Article Dedicated to Professor Matthias Beller on the occasion of his 60 birthday Graphical Abstract A Pd0-catalyzed asymmetric carbonitratation reaction between (Z)-1-iodo-1,6-diene and AgNO3 has been developed with the use of [PyH][BF4] as H-bonding donor under the toluene/H2O biphasic conditions, which provides a complementary method towards alkyl nitrates with high enantioselectivity.
Efficient synthesis of isoquinolines in water by Pd-catalyzed tandem reaction of functionalized alkylnitriles with arylboronic acids
A palladium-catalyzed tandem reaction of 2-(cyanomethyl)benzonitriles or 2-(2-carbonylphenyl)acetonitriles with arylboronic acids in water has been developed for the first time. This reaction features good functional group tolerance and provides a new strategy for the synthesis of diverse isoquinolines under mild conditions. The use of water as the reaction medium makes the synthesis process environmentally benign.
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