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Articles by Linus Chiang
Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites
Conflict of Interests The authors declare no conflict of interest. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
NiII and CuII complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere
NiII and CuII complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere† Rachel Sailer,a Warren VandeVen, b Kaeden Teindl‡a and Linus Chiang *a Abstract Herein, we report the synthesis, spectroscopic characterization and electrochemical investigation of the NiII and CuII complexes of a novel Sal ligand bearing two ferrocene moieties attached at its diimine linker, M(Sal)Fc. The electronic spectra of M(Sal)Fc are near identical to its phenyl-substituted counterpart,...
Stabilization of different redox levels of a tridentate benzoxazole amidophenoxide ligand when bound to Co(III) or V(V)
Stabilization of different redox levels of a tridentate benzoxazole amidophenoxide ligand when bound to Co(III) or V(V) A tridentate benzoxazole-containing aminophenol ligand NNOH2 was coordinated to Co and V metal centers and the electronic structure of the resultant complexes characterized by both experimental and theoretical methods.
Exclusive imidazole ligation to CuIII2O2 and CuIIICuII2O2 cores
Exclusive imidazole ligation to CuIII2O2 and CuIIICuII2O2 cores You have access to this article Please wait while we load your content... Something went wrong. Try again?
Characterization of an oxidized Mn(III)-bis(phenolate)dipyrrin Radical Complex and Oxidation Catalysis Control via Ligand-centered Redox Activity
The tetradentate ligand dppH3, which features a half-porphyrin and two electron-rich phenol moieties was prepared and chelated to manganese. The mononuclear Mn(III)-dipyrrophenolate complex 1 was structurally characterized. The metal complex is square pyramidal, with the apical position being occupied by a methanol molecule. Complex 1 displays two reversible oxidation waves at 0.00 V and 0.47 V vs. Fc+/Fc, which are assigned to ligand-centered processes.
Synthesis and Electronic Structure Determination of Uranium(VI) Ligand Radical Complexes
Pentagonal bipyramidal uranyl ([UO2]2+) complexes of salen ligands, N,N’-bis(3-tert-butyl-(5R)-salicylidene)-1,2-phenylenediamine, in which R = tBu (1a), OMe (1b), and NMe2 (1c), were prepared and the electronic structure of the one-electron oxidized species [1a-c]+ were investigated in solution. The solid-state structures of 1a and 1b were solved by X-ray crystallography, and in the case of 1b an asymmetric [UO2]2+ unit was found due to an intermolecular hydrogen bonding interaction.
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