Is this you? As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.
Claim your profile
Articles by Mark Murrie
Polyoxometalates as advanced-performance anions for ∼D5h Dy(III) single-ion magnets
Polyoxometalates as advanced-performance anions for ∼D5h Dy(iii) single-ion magnets† We enhance single-ion magnet (SIM) magnetisation reversal barriers by engineering the second coordination sphere, substituting conventional small monoanions with a bulky polyoxometalate (POM) trianion. Importantly, our approach serves as a model for creating new high-performance multifunctional hybrid materials. This article is Open Access This article has not yet been cited.
Self-assembly of Schiff Base Anions and Trapping of HO−, O2− and Piv− Bridges in a Family of Ni3Ln4 Complexes: Synthesis, Structures and Magnetic Properties
Self-assembly of Schiff Base Anions and Trapping of HO−, O2− and Piv− Bridges in a Family of Ni3Ln4 Complexes: Synthesis, Structures and Magnetic Properties Mousumi Biswas, Athanasios Mavromagoulos, Mark Murrie and Debashis Ray Abstract A unique family of heptanuclear 3d-4f complexes, [Ni3Ln4L3(OH)3O(Piv)6(MeOH)2(MeO)]·nH2O (Ln = Dy, 1; Tb, 2; Ho, 3; Piv = Me3CCO2−), has been synthesized using Schiff-base H2L (L = 2-((2-hydroxy-3-methoxybenzylidene)amino)benzoic acid), NEt3, NiCl2∙6H2O and...
Elucidating the exchange interactions in a {GdIIICuII4} propellor
Elucidating the exchange interactions in a {GdIIICuII4} propellor Mark Murrie, María José Heras Ojea, Claire Wilson, Jordi Cirera, Hiroki Oshio and Eliseo Ruiz Abstract The multinucleating ligand 2,2'-(propane-1,3-diyldiimino)bis[2-(hydroxymethyl)-propane-1,3-diol] (Bis-tris propane, H6L) is used in the design of a new family of 3d-4f complexes that display an unusual {LnCu4} four-blade propeller topology.
Solvent-induced structural transformation from heptanuclear to decanuclear [Co-Ln] coordination clusters: trapping of unique counteranion and understanding of aggregation pathways - Dalton Transactions (RSC Publishing)
Solvent-induced structural transformation from heptanuclear to decanuclear [Co–Ln] coordination clusters: trapping of unique counteranion and understanding of aggregation pathways† Dipmalya Basak,a Emma Regincós Martí,b Mark Murrie, b Ivan Nemec cd and Debashis Ray *a Author affiliations * Corresponding authors a Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India E-mail: dray@chem.iitkgp.ac.in Fax: (+91) 3222-82252 Tel: (+91) 3222-283324 b School of Chemistry,...
Engineering macrocyclic high performance pentagonal bipyramidal Dy(III) single-ion magnets
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(III) Single-Ion Magnet
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets - Murrie - - Angewandte Chemie International Edition - Wiley Online Library
Communication Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets Mark Murrie Corresponding Author E-mail address: mark.murrie@glasgow.ac.uk University of Glasgow, School of Chemistry, University Avenue, G12 8QQ Glasgow, UNITED KINGDOM Search for more papers by this author PDF PDF Share Abstract Following a novel synthetic strategy where the strong uniaxial ligand field generated by the Ph3SiO‐ (Ph3SiO‐ = anion of...
Investigation of the magnetic anisotropy in a series of trigonal bipyramidal Mn(II) complexes
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(II)
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
Microwave-assisted synthesis: from a mononuclear {CoII} complex to {CoII9} solvomorphs
Microwave-assisted synthesis: from a mononuclear {CoII} complex to {CoII9} solvomorphs Alexandra Collet,a Claire Wilsona and Mark Murrie*a Abstract We report a new {CoII9} complex with an unprecedented structure and its solvated analogue, using microwave heating to tune the synthesis and improve the product selectivity.
Microwave−assisted synthesis: from a mononuclear {CoII} complex to {CoII9} solvomorphs
We report a new [Co ] complex with an unprecedented structure and its solvated analogue, using microwave heating to tune the synthesis and improve the product selectivity
Strategic Synthesis of [Cu2], [Cu4] and [Cu5] Complexes: Inhibition and Triggering of Ligand Arm Hydrolysis and Self-aggregation by Chosen Ancillary Bridges
The Schiff base ligand HL1 ({2,6-bis(allylimino)methyl}-4-methylphenol) having no coordinating donor arm has been examined for its reaction medium and ancillary bridge dependent reactivity for hierarchical family of Cu complexes. The ligand showed unique reactivity pattern toward Cu in solution.
Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre
We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.
Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(II) under high pressure
Understanding and controlling magnetic anisotropy at the level of a single metal ion is vital if the miniaturization of data storage is to continue to evolve into transformative technologies. Magnetic anisotropy is essential for a molecule-based magnetic memory as it pins the magnetic moment of a metal ion along the easy axis. Devices will require deposition of magnetic molecules on surfaces, where changes in molecular structure can significantly alter magnetic properties.
Ligand-directed synthesis of {MnIII5} twisted bow-ties
Two isostructural polymetallic complexes [MnIII5(?3?O)2(CH3COO)4(L1)4]? and [MnIII5(?3?O)2(CH3COO)4(L2)4]? have been synthesised by using two Schiff base ligands derived from 3,5?diamino?1,2,4?triazole, following two different preparative routes, either using the pre?formed ligand (for L1) or via a metal?mediated template synthesis (for L2). The {MnIII5} structure is unusual, being based on two corner?sharing perpendicular {Mn3} triangles forming a twisted bow?tie.
Dalton Transactions
A. Canaj, M. Siczek, T. Lis, M. Murrie, E. K. Brechin and C. J. Milios, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT01883E If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using RightsLink. Go to our Instructions for using RightsLink page for details.
Rational serendipity: ‘‘undirected’’ synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks
We welcome your comments for improvement of this site and our services. Please enter the characters in the box below as you see them. Thank you for helping us improve our site.
Show More
loading
Actions
Is this you?
As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.Get in touch with Mark
Contact Mark, search articles and posts on X, monitor coverage, and track replies from one place.
Learn more about Muck Rack