Is this you? As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.
Claim your profile
Articles by Matthew B. Plutschack
Where is chemistry's moon? Highlights from the 1st conference for the Center of the Transformation of Chemistry (CTC) at Ringberg Castle 2023
Where is chemistry's moon? Highlights from the 1st conference for the Center of the Transformation of Chemistry (CTC) at Ringberg Castle 2023 In 2023, the Center for the Transformation of Chemistry (CTC) began a three-year start-up phase, aiming to draft its research program. The CTC-Conference at Ringberg brought scientists together to discuss their research and brainstorm a “moon-shot” program to align efforts, enable rapid discoveries, and move towards a sustainable circular economy.
Regio‐ and Stereoselective Thianthrenation of Olefins to Access Versatile Alkenyl Electrophiles
Communication Tobias Ritter Corresponding Author E-mail address: ritter@mpi-muelheim.mpg.de Max-Planck Institut fuer Kohlenforschung, Department of Organic Chemistry, Kaiser-Wilhelm-Platz 1, 45470 Muelheim an der Ruhr, GERMANY Search for more papers by this author PDF PDF Share Abstract Here we report a regioselective alkenyl electrophile synthesis from unactivated olefins via a direct and regioselective C–H thianthrenation reaction.
Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination
Abstract Photoredox catalysis, especially in combination with transition metal catalysis, can produce redox states of transition metal catalysts to facilitate challenging bond formations that are not readily accessible in conventional redox catalysis. For arene functionalization, metallophotoredox catalysis has successfully made use of the same leaving groups as those valuable in conventional cross-coupling catalysis, such as bromide.
Site-selective and versatile aromatic C−H functionalization by thianthrenation
Abstract Direct C–H functionalization can quickly increase useful structural and functional molecular complexity1,2,3. Site selectivity can sometimes be achieved through appropriate directing groups or substitution patterns1,2,3,4—in the absence of such functionality, most aromatic C–H functionalization reactions provide more than one product isomer for most substrates1,4,5.
High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation
59 Reactions of dimethyl sulfoxide. I. Synthesis of dimethyl-hydroxyarylsulfonium halides and their pyrolysis to methyl hydroxyaryl thio ethers Goethals, E.; Radzitzky, P. de Bulletin des Societes Chimiques Belges (1964), 73 (5-6), 546-59CODEN: BSCBAG; ISSN:0037-9646. A series of 15 (ArSMe2)+Cl-(I) was prepd. by condensing Me2SO and phenols with HCl. The structure of the resulting I and the mechanism of their formation are discussed. The pyrolysis of the I yielded quant. the corresponding ArSMe (II).
Show More
loading
Actions
Is this you?
As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.Get in touch with Matthew B.
Contact Matthew B., search articles and posts on X, monitor coverage, and track replies from one place.
Learn more about Muck Rack